Introduction

An Introduction to Polymer Colloids by Mohamed S. El-Aasser (auth.), Françoise Candau, Ronald H.

By Mohamed S. El-Aasser (auth.), Françoise Candau, Ronald H. Ottewill (eds.)

The progress of curiosity within the topic of Polymer Colloids over the past twenty 5 years or so has been very huge ensuing now in significant overseas meetings on an annual foundation and plenty of nationwide ones to boot. The curiosity stems not just from the wide variety of purposes of those fabrics but additionally from a interest as to the mechanism of formation and their growing to be use as version debris to enquire primary features of physics and chemistry. In July 1988 a NATO complicated examine Institute was once held in Strasbourg, France, on the Centre St. Thomas. As an academic creation to this I nstitute a chain of 8 lectures was once given to hide the elemental elements of the topic. those 8 lectures have now been compiled into an Introductory textual content protecting, emulsion poly­ merization, dispersion polymerization, inverse emulsion polymerization, the morphology of copolymer latices, the colloidal homes of latices, characterization tools and rheology. it truly is was hoping that those will serve a large viewers, undergraduates, graduate-students and study staff, either in and academe. The chapters all include overview fabric brand new on the time of ebook. fhe 1988 NATO complicated examine I nstitute was once made attainable through a supply from the NATO-AS I programme and the subsequent businesses: BASF, Ludwigshafen, West Germany The Dow Chemical corporation, Michigan, united states Dow Chemical Rheinwerk GmbH, Rheinmunster, West Germany ICI PLC, Runcorn, England S. C. Johnson and Son Inc., Racine, united states NORSOLOR, Verneuil en Halatte, France Rhone Poulenc, Aubervilliers, France.

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Dispersion Polymerization in Organic Media, Wiley, New York, 1975. H. , 1987, 10/11, 503. G. , 269. Feeney, P. , Napper, D. H. and Gilbert, R. , 2520. H. lQl, 159. Feeney, P. , Napper, D. H. and Gilbert, R. , Macromolecules, 1987, zg", 2922. W. l, 703. S. , 1973, lli, 503. D. , 1985,~, 2973. M. , in Emulsion Polymerization, Eds. I. L. Gardon, ACS Symposium Series, Vol. C. 1976. A. , 1986,~, 861. §" 591. W. , Colloid and Surfaces, 1984, llt 79. A. , 1989, 27, 193. Polymere, 1970, 239, 677; 32 49.

Expressions (251 for the rate of initiation (Ri I and propagation (Rp I have been derived and are given in Equations (11 and (21 respectively. (11 and , Rp = kp[M]( R1 12k/2 (2 ) where f is the initiator efficiency, kd is the rate constant for the decomposition of initiator, [I] is the initiator concentration, [M] is the 52 80 z Q (I) a: 60 / I&J > Z 040 u 20 b I / yc / /---~ ~-­ OL---~~~--'~~~~~-~----~~~-=-~~~--~ o Figure 10: Shows a comparison of the conversion-time curves for (a I the dispersion polymeri zation, (b I the precipitation polymerization of methyl methacrylate in an aliphatic hydrocarbon medium, while (cl shows the conversion-time curve for the solution polymerization of methyl methacrylate in benzene.

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